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World's smallest balloon inflated

A carbon membrane only a single atom thick has been used to create a pressurised "balloon" that is impermeable to gas.

To make it, researchers at Cornell University in Ithaca, New York inflated a sheet of graphene. This is a recently discovered carbon material just one atom thick, and is tipped to succeed silicon as the basis of computing.

They created the sheets of graphene using a low-tech process dubbed "mechanical exfoliation" - using sticky tape to peel layers from a chunk of graphite.

The sheets were used to seal microscopic wells made in a layer of silica glass, forming a kind of drum head. The membranes were held in place only by the van der Waals forces that make things sticky at microscopic scales. The wells varied from 1 to 100 square micrometers in area and 250 nanometres to 3 micrometers deep.

To see how well the graphene could hold in gas, the researchers altered the pressure inside, making the graphene membranes bulge outward or inward.

Leak free

The membranes were able to withstand pressure differences of up to several atmospheres before being dislodged. But as long as the seal remained, the graphene was completely impermeable.

Gas did leak in or out over several days, but the researchers discovered that it was leaving through the glass, not the membranes.

By measuring exactly how much the graphene bulged under a specific pressure, the researchers were able to calculate its elasticity, which turns out to be the same as that of normal graphite.

They also used a laser to vibrate the membrane and measure its resonance frequency, which provides a way to calculate the exact mass of the graphene.

Paul McEuen, a physicist at Cornell and a co-author of the paper, says that process means the setup could be used as a tiny weighing device. Graphene balloons could also be used as tiny pressure sensors, he adds.

Promising material

James Hone, a physicist at Columbia University in New York, calls inflating the tiny balloons "very nice work".

Hone thinks graphene clearly has more to offer than just its impressive electronic properties. "I think what we're learning from all these measurements is that graphene really does live up to its promise as a mechanical material. It really does outperform by orders of magnitude anything out there," he says.

Journal reference: Nano Letters (DOI: 10.1021/nl801457b)

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Have your say
Comments 1 | 2

Graphene Was Not Recently Discovered!

Fri Aug 08 21:27:21 BST 2008 by Cyrus

Graphene may be all the talk nowadays, but to say it was recently discovered is nonsense! The structure of graphite as layers of 2-dimensional hexagonal based sheets has been known for quite some time. I was tought about this in university 20 years ago.

It's only just recently that the great minds of science have figured out how to isolate the material by their new high tech methodology - Scotch tape.

Graphene Was Not Recently Discovered!

Fri Aug 08 22:56:15 BST 2008 by Brice

There is quite a bit of difference between describing the way graphite sheets are held together as a solid (which has been known for many years) and actually isolating graphene. Before it was isolated, one could argue that "graphene", a stand-alone one-dimensional crystal, had not been discovered. In fact, most people figured that graphene could not exist and would just curl up into a buckyball.

Graphene Was Not Recently Discovered!

Tue Aug 12 16:14:30 BST 2008 by Michael Marshall, Online Editorial Assistant

Brice has it right. As you say, the layered structure of graphite is well-established, but it was only a few years ago that it was discovered that graphene sheets could exist independently. If we use the word "graphene" to mean a single such sheet in isolation, then it was definitely only discovered recently. :) See for instance (long URL - click here)

A Very Happy Bill Gates:

Fri Aug 08 22:37:28 BST 2008 by Microsoft

This comment has been found to be in breach of our terms of use and has been removed.

Happy Graphene

Sat Aug 09 03:48:39 BST 2008 by Ron Horgan

How marvellous, every week there is something new and unexpected to enjoy. What a great piece of work, opening yet another door.

Comments 1 | 2

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Atomic force microscope images of gas-filled balloons just one carbon atom thick (top), or made using several layers of carbon (bottom). The membranes are impermeable and do not leak (Images: American Chemical Society)

Atomic force microscope images of gas-filled balloons just one carbon atom thick (top), or made using several layers of carbon (bottom). The membranes are impermeable and do not leak (Images: American Chemical Society)

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